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What is it, how do we make it, and what is it good for
Recently a reader (I have a Reader!) wanted to know more
about hydrogen. I provided a quick answer, offering to dig a little deeper if
useful. So here goes. There will be a bit of basic chemistry which I hope I
have simplified sufficiently. Ultimately every bit of analysis here relates to
energy: where does it come from, what does it cost, and what are the greenhouse
gas emission implications; and generating energy often involves the chemistry
of combustion. After all, 75% of total world greenhouse gas emissions are
related to energy production and use.
Hydrogen is the name of an atom, with the symbol H, as well
as the name of a molecule made up of two hydrogen atoms, H2. Similarly, two
oxygen atoms O pair up to make an oxygen molecule O2. Hydrogen, like a lot of
things, will burn in an oxygen atmosphere. The chemists call this process
“oxidation”, because the stuff being burned is broken up into smaller units
which combine with the oxygen in the air. Combustion, or oxidation, releases a
lot of heat, which is why it is useful. So oxidising hydrogen looks like this:
2 H2 + O2 → 2 H2O
This simply says that 2 molecules of hydrogen H2,
containing a total of 4 atoms of hydrogen, combine with a molecule of oxygen O2,
containing two atoms of oxygen, to make two molecules of H2O, also
known as water. (Both sides of this equation contain four hydrogen atoms and
two oxygen atoms, so it is balanced – we haven’t created or destroyed any
atoms. This is a basic concept called conservation of mass.)
The interesting thing about this is that there is no carbon
anywhere in the process, so there is no opportunity to oxidise carbon to carbon
dioxide (CO2); the only emission is water vapour. (Combustion in
air, which contains nitrogen as well as oxygen, is a bit more complicated, but
we’ll leave that aspect for another day.) From a greenhouse gas perspective,
this appears to be a winner: heat without CO2 generation.
But the real question is where the hydrogen comes from.
Production and transportation of hydrogen both require energy, potentially
creating a GHG impact.
Hydrogen: how is it made
There are several ways of obtaining hydrogen, which isn’t
just lying around – it tends to react with oxygen pretty quickly and turn to
water. It is also a key part of fossil fuels. The two major approaches to
making pure hydrogen molecules are to break up the water molecule that we just
made above, or to break up a hydrocarbon molecule of some sort. We’ll start
with the hydrocarbon path.
Natural gas is the simplest hydrocarbon, being made up of a
carbon atom and 4 hydrogen atoms: CH4. This molecule is also known
as methane. Separating hydrogen from methane is done with two reactions, the
first called steam reforming (see the Wikipedia article for more information, click
here):
CH4 + H2O → CO + 3 H2
In this reaction, methane and water (in the form of steam)
combine to generate one molecule of carbon monoxide (CO) and three hydrogen
molecules. The carbon monoxide is a nuisance, so more water is added (this is
called the water gas shift reaction):
CO + H2O → CO2 + H2
So overall we’ve used two water molecules and a methane
molecule to make four hydrogen molecules and one molecule of carbon dioxide (CO2).
While the chemists will scream that this is not an accurate representation of
what happens at the molecular level, the following illustrates the overall combined
mass balance of the two reactions:
CH4 + 2 H2O → CO2 + 4 H2
If you are burning hydrogen made using this way, your
tailpipe or smokestack emissions may consist only of water vapour, but you have
generated greenhouse gas emissions (one carbon dioxide emitted for every four
hydrogen molecules generated) somewhere else.
It is worth noting that similar processes can be applied to
most carbon-containing materials, such as wood chips, oil, coal, etc. (For
those interested, look up gasification and the Fischer-Tropsch process.) If the
material comes from plants, for example wood chips, the process is presumed to
be greenhouse gas neutral, as the CO2 emitted is presumed to have
been pulled out of the air when the plant grew; the assumption is that we are
not putting new carbon (from fossil sources) into the atmosphere, but simply
returning carbon to the atmosphere that was there until the seedling took root.
This assumption comes with a certain amount of hand waving and deserves a
deeper dive in a future article.
It is also worth noting that unlike combustion, which
generates heat, this reaction, like baking a cake, requires heat: there is an
energy cost to this approach.
The proponents of this approach counter the GHG argument by
proposing a technology called carbon capture, use and sequestration (CCUS) to
redirect the CO2 back into the ground. But this technology is an expensive
energy hog which doesn’t remove 100% of the carbon dioxide in a gas stream, and
which remains to be proven at large scale. The whole objective needs to be a
smarter use of energy, and using lots of energy to make more energy is
problematic in my view, especially if it isn’t a zero-carbon approach. We also
need technologies that work now, as time is getting very short.
The second path involves reversing the combustion process
described above. If that process created heat, i.e. energy, reversing it needs
energy. Typically this involves a process called electrolysis (you can also
look this up on Wikipedia, click here) which requires a lot of electricity. The result is the generation of molecules
of oxygen and hydrogen which need to be separated to prevent them combining
again:
2 H20 →2 H2 + O2
This approach generates no carbon dioxide, as long as the
power is not generated with fossil fuels; if power is fossil-based, once again we
have simply shifted the emissions elsewhere.
Hydrogen: How would we use it if we had a lot of it
Hydrogen is a very dilute gas and needs to be compressed to
very high pressures in order to get a reasonable amount of energy into a
reasonable sized reservoir, such as a vehicle fuel tank. So beyond the energy
required to make it, there is the energy required to compress it.
Furthermore, it is highly explosive. Oxidation as described
above happens very quickly and can make a huge mess if there is enough hydrogen
available. Think of your barbecue propane tank on steroids, or Google
“Hindenburg disaster” for a preview. So safe handling is a major issue. For
this reason, I think using hydrogen to fuel vehicles is a major disaster
looking for an opportunity to happen; Hollywood movies notwithstanding, a
ruptured gasoline tank burns nice and hot but a ruptured pressurised hydrogen
tank can fling hot, flaming shrapnel over distances of hundreds of metres,
potentially killing or injuring many random bystanders.
Hydrogen is used in the production of a range of
petrochemicals and fertilisers. These are non-combustion processes and generate
no GHGs, except in the production of any energy required to run the reactions
in question; they take place in large industrial sites where occupational
health and safety (OH&S) procedures for dealing with high pressure
flammable gasses are in place, so we’ll leave these for another day. But I will
point out that this will be a problem eventually as the hydrogen used in these
processes typically arises as a byproduct of oil refinery operations: if we
stop burning gasoline and diesel, which we should, this source of hydrogen may
disappear. So these users may eventually need to find new hydrogen sources.
Hydrogen could replace fossil fuels in a variety of
industrial processes such as steel or cement making. If these large industrial
users have access to green power (hydro, solar or wind), hydrogen production
onsite from water begins to make sense. The hydrogen would then be used onsite,
with no pipeline or tanker transport required, in situations where
industrial-grade OH&S procedures are in place to prevent an explosion.
It has been suggested that hydrogen could be distributed via
the existing natural gas pipeline network to homes and factories across the
continent, but this requires assurance that every single inch of pipe in the
network is made of steel grades that resist hydrogen embrittlement, a condition
where hydrogen attacks and weakens steel. And when I say every inch, I mean
right to the burner tip in every gas appliance connected to the grid, whether
domestic, institutional, commercial or industrial. To my mind, this creates an
unacceptable risk to the public unless a local green hydrogen production
facility is paired with new pipelines to new developments.
Hydrogen’s place in a Net Zero world
So there you have it: Hydrogen is best used on large
industrial sites, where it can be made onsite from water using green
electricity. Onsite storage and use can be regulated through OHSA or other
regulatory bodies to eliminate safety risks to the public. The benefits are
decarbonising large industrial processes for which there aren’t really any
immediately obvious substitutions available today.
Hydrogen use in vehicles is possible but the safety issues
are huge. The same is true if we try to put hydrogen into the existing natural
gas pipeline network.
Hydrogen from natural gas raises uncomfortable questions
around fugitive methane emissions, carbon capture at less than 100% levels, and
high levels of complexity, cost and energy demand. In particular, the cost per
tonne of CO2 abated, the so-called carbon index, should be a guide:
Could those dollars and energy resources be better invested elsewhere, with
greater levels of GHG reductions per dollar spent? And the technology is not
yet proven at large scales; arguably we don’t have the time to sit around and
hope it all works.
I hope I’ve answered my Reader’s questions; and I would be
happy to try to answer yours too! Please write, especially if you feel this
outline has been excessively or insufficiently simplistic.